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Double-encapsulation structures create multifunctional flame-retardant, antibacterial, and hydrophobic cotton fabrics

Researchers have developed a bio-based double-encapsulation strategy using β-cyclodextrin and L-arginine to produce cotton fabrics with flame-retardant, antibacterial, and hydrophobic properties, meeting diverse application demands.

Double-encapsulation structures enhance cotton fabrics with flame-retardant, antibacterial, and hydrophobic capabilities. Source: silencefoto – stock.adobe.com.

The increasing adoption of biomass-derived materials is addressing challenges associated with non-renewable petroleum resources while opening new possibilities for multifunctional textile applications. This study introduces a bio-based double-encapsulation strategy combining β-cyclodextrin (β-CD) and L-arginine to synthesise a multifunctional additive, β-TPLA, with flame-retardant and antibacterial properties. Additionally, nano-TiO₂ particles were encapsulated using β-CD, and a fluorine-free polysiloxane (POSI) copolymer was created to impart durable hydrophobicity.

The finished cotton fabrics achieved a high limiting oxygen index (35.2 %) and demonstrated excellent self-extinguishing capabilities due to synergistic gas-phase and condensed-phase mechanisms. Antibacterial tests revealed inhibition rates of 97.3 % against Escherichia coli and 98.1 % against Staphylococcus aureus, while the fabrics retained hydrophobic properties with a water contact angle of 124.5°. Notably, the treated cotton maintained good whiteness and mechanical strength, providing a sustainable and effective solution for high-performance textile applications.


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Expanded applications for industry and beyond

This eco-friendly and scalable finishing process enhances cotton fabrics for use in diverse fields, including protective clothing, medical textiles, and outdoor fabrics. The study highlights the potential of bio-based strategies in developing multifunctional textiles with advanced properties, supporting sustainable innovation in the coatings and textiles industries.

Source: Liu, X. et al., “Double-encapsulation” structures with dual biomass components for flame-retardant, antibacterial and hydrophobic cotton fabrics. Progress in Organic Coatings, 109880 (2025).