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Janus particle microcapsules enable innovative anti-icing coating with photothermal and superhydrophobic properties

Researchers have developed a multifunctional anti-icing coating that combines Janus particles and phase-change microcapsules to store thermal energy, efficiently utilise solar energy, and ensure outstanding mechanical durability.

An anti-icing coating with Janus particles provides effective thermal storage, solar energy absorption, and lasting superhydrophobicity. source: Rico Ködder - Adobe.Stock

Photothermal superhydrophobic coatings hold great promise for anti-icing and de-icing applications but face limitations such as intermittent sunlight exposure and leakage from encapsulated phase-change materials. This study introduces a novel solution: Janus particles (JPs) encapsulating n-octadecane (C18) in microcapsules that integrate photothermal conversion with thermal energy storage.

Using emulsion polymerisation and phase separation, the particles were structurally anchored with epoxy-Silica@PS/PDVB, forming a rivet-like structure. The microcapsules demonstrate a melting latent heat of 91.02 J/g and a crystallisation latent heat of 83.9 J/g, highlighting their thermal reliability. Under sunlight, the coating increases the surface temperature by approximately 20 °C within 400 s, while the phase-change materials slow temperature changes and delay freezing.


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Mechanical durability and anti-icing efficiency

The coating achieves a water contact angle of 155.59° and a sliding angle of only 5°, maintaining its superhydrophobicity and self-cleaning ability after 100 abrasion cycles. These properties make it ideal for low-temperature, high-humidity environments. The research provides new insights into high-performance phase-change materials and innovative anti-icing coating design.

Source: Ma, H. et al., A highly efficient anti-icing/de-icing surface designed with Janus particle encapsulated phase-change microcapsules exhibits photothermal performance and superhydrophobicity. Progress in Organic Coatings, 109892 (2025).