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22. Oct 2021 | Application Areas

Making cotton fabrics more durable in outdoor environments

Scientists have investigated UV-curable cellulose acetate butyrate-based oligomers and their use for cotton fabric coatings.
The coated fabrics were evaluated in terms of abrasion, thermal conductivity, and air and water vapor permeability properties. 
Image source: StockSnap - Pixabay (symbol image).

In order to improve the thermal stability and flexibility, cellulose acetate butyrate (CAB) was modified with toluene diisocyanate–hydroxyethyl methacrylate (TDI–HEMA) adduct in various molar ratios. The obtained oligomer was characterised by proton nuclear magnetic resonance (1H NMR) and Fourier transform infrared (FTIR) spectroscopies. Gloss, cross-hatch, contact angle, and Taber abrasion tests were all used to investigate the film forming performance of the modified CAB oligomers on glass plates.

The UV-cured free films of the synthesised oligomers were examined in terms of the mechanical tests. By using the synthesised CAB oligomers, coating formulations were prepared and applied onto cotton fabrics in order to make the cotton fabrics more durable in outdoor environments. The existence of the coating layer on the fabric surfaces was investigated by scanning electron microscopy (SEM).

Good mechanical poperties

The coated UV-cured fabrics were evaluated separately in terms of abrasion, thermal conductivity, and air and water vapor permeability properties. Results proved that the oligomer (50%-CAB) in which 50% of the hydroxyl groups of CAB were reacted with TDI–HEMA adduct showed the best mechanical properties with the highest tensile strength and modulus values. Considering the coated fabrics, the least deformation against abrasion, the highest air/water vapor permeability, and the best thermal conductivity were all recorded in 50%-CAB coated sample.

The study has been published in Journal of Coatings Technology and Research, Volume 18, 2021.

Resins for water-borne coatings - EC Library


Resins for Water-borne Coatings

Expand your knowledge and get fully acquainted with the various aspects of water-borne coatings - from production to properties to special features of their use! With the slow change from solvent-borne resins and coatings to water-borne coatings "Resins for waterborne coatings" is a must-read for any formulator wanting to expand their knowledge. The authors discuss important aspects of the "solvent-to-water-transition" of the past 40 to 50 years, take a deep dive into the key aspects and theories behind the production, properties and applications of these resins as well as providing an overview of how they are currently used in water-borne coatings.

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