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Saturday, 20 July 2019
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Raw materials & technologies, Technologies, Nanotechnology

Natural nanocrystals shown to strengthen concrete

Wednesday, 8 April 2015

Cellulose nanocrystals derived from industrial byproducts have been shown to increase the strength of concrete, representing a potential renewable additive to improve the ubiquitous construction material.

This transmission electron microscope image shows cellulose nanocrystals. Source: Purdue Life Sciences Microscopy Center

This transmission electron microscope image shows cellulose nanocrystals. Source: Purdue Life Sciences Microscopy Center

The cellulose nanocrystals (CNCs) could be refined from byproducts generated in the paper, bioenergy, agriculture and pulp industries. They are extracted from structures called cellulose microfibrils, which help to give plants and trees their high strength, lightweight and resilience.

Creating a new class of biomaterials

Now, researchers at Purdue University have demonstrated that the cellulose nanocrystals can increase the tensile strength of concrete by 30 percent. "This is an abundant, renewable material that can be harvested from low-quality cellulose feedstocks already being produced in various industrial processes," said Pablo Zavattieri, an associate professor in the Lyles School of Civil Engineering. The cellulose nanocrystals might be used to create a new class of biomaterials with wide-ranging applications, such as strengthening construction materials and automotive components.

Nanocrystals increase hydration

One factor limiting the strength and durability of today's concrete is that not all of the cement particles are hydrated after being mixed, leaving pores and defects that hamper strength and durability. "So, in essence, we are not using 100 percent of the cement," Zavattieri said. However, the researchers have discovered that the cellulose nanocrystals increase the hydration of the concrete mixture, allowing more of it to cure and potentially altering the structure of concrete and strengthening it.  As a result, less concrete needs to be used. The cellulose nanocrystals are about 3 to 20 nanometers wide by 50-500 nanometers long - or about 1/1,000th the width of a grain of sand - making them too small to study with light microscopes and difficult to measure with laboratory instruments. They come from a variety of biological sources, primarily trees and plants.

Forming little inlets for water

The concrete was studied using several analytical and imaging techniques. Because chemical reactions in concrete hardening are exothermic, some of the tests measured the amount of heat released, indicating an increase in hydration of the concrete. The researchers also hypothesized the precise location of the nanocrystals in the cement matrix and learned how they interact with cement particles in both fresh and hardened concrete. The nanocrystals were shown to form little inlets for water to better penetrate the concrete.

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