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Thursday, 19 September 2019
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Raw materials & technologies, Technologies

Flexible bio-based acrylates coatings

Tuesday, 18 September 2018

Researchers have developed promising acrylate coatings with cardanol-modified fatty acids from camelina oils.

The acrylate obtained from cardanol-modified fatty acids from camelina oil is a good alternative to AESO. Source: margenauer / Pixabay.

The acrylate obtained from cardanol-modified fatty acids from camelina oil is a good alternative to AESO. Source: margenauer / Pixabay.

Novel bio-based acrylate was designed through the epoxy ring-opening reaction of cardanol glycidyl ether (CGE) with fatty acids from camelina oil (FACO), followed by epoxidation of unsaturated chains and then acrylation of the epoxides. Cardanol- and camelina oil-based acrylates were also respectively synthesised for comparison purposes. The bio-based acrylate coatings were then produced under UV-radiation from the acrylates monomers with an addition of a photoinitiator.

Evaluation of mechanical and thermal properties

Polymerisation of the acrylates and synthesis of the monomers were observed using Fourier transform infrared (FTIR) spectroscopy, and the chemical structures and acryl contents of the acrylates were confirmed by proton nuclear magnetic resonance (1H NMR). The mechanical and thermal properties of the cured acrylates were evaluated using tensile test, dynamic mechanical analysis (DMA), and thermogravimetric analysis (TGA). Observation of resistances to water, solvent, and hydrolytic degradation were conducted to water and toluene uptake test, methyl ethyl ketone (MEK) rub test, and a degradation test under sodium hydroxide solution.

A good alternative to soy oil

Gel content was measured to evaluate performance of the coatings, and other coating performances including gloss, adhesion, and pencil hardness were determined using the wood panel coated with the cured acrylates. Compared to acrylated epoxidised soybean oil (AESO) coating, the acrylate derived from the cardanol modified fatty acids showed higher tensile strength, hardness, glass transition temperature, thermal decomposition temperature at maximum degradation rate, and resistances to solvent and hydrolytic condition of the cured coating. Therefore, the newly designed acrylate is a great alternative to AESO.

The study is published in: Progress in Organic Coatings Volume 123, October 2018, Pages 242-253.

Event tip:

The seminar "Bio-based raw materials" will give you an comprehensive insight into renewable materials for the coatings industry.

 Image source: Pixabay

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